The problem I recall was with smaller Lycomings & especially Continentals in the early - mid '70s during the transition from 100/130 to 100LL. The lower lead content in 100LL wasn't lubing the valves as well as the 100/130 was, IIRC, 100LL has only about 25% of the lead that 100/130 had, & people were having valves sticking every time they turned around. In later years, new valves were made using different metals that pretty much eliminated the sticking problems. I don't know if the bigger engines had that problem tho.
warbirddriver wrote:
Lead is some bad-ass nasty stuff. But I have never seen any reliable data that suggests that lead is/was a lubricant in anyway.
Fair cop! I'm no chemist / engineer Glenn, so I put the lube in quotes. However this is a reference to my understanding of the point, the bit related to my previous point being highlighted, but a rider specific about lubrication coming after as well - the latter not my original thought, I should add. Lubrication may not be the best/correct term, but it does get used in this context. Better explanations welcome!
Quote:
But leaded petrol had even more benefits. As it burns, tetraethyl lead turns into a tan-coloured layer of lead oxide, which covers the valves and the combustion chamber. The valves hit hard against the valve seats several thousand times each minute. The lead oxide acts as a cushioning agent, and protects the valve and the valve seats. The lead oxide is also a lubricating agent. This reduces wear in the valve guides, as the valves slide inside them.
If you start running your old leaded engine on unleaded petrol, the lead oxide quickly wears away. Damage begins, but only if your engine was made with "soft" metallurgy, and only in high-temperature areas - exhaust valves, exhaust valve guides and exhaust valve seats.
http://abc.com.au/science/k2/trek/4wd/lead2.htm